While physisorption is highly effective for removing volatile organic compounds and odours, it falls short in environments where corrosive gases pose a threat to sensitive equipment and processes. In industrial applications such as data centres, refineries, and control rooms, the solution lies in chemisorption, a process where gases are not just captured, but chemically transformed into safer compounds.
What is Chemisorption?

Chemisorption is the process by which gas molecules react chemically with the surface of an adsorbent medium, forming strong chemical bonds. Unlike physisorption, this process is irreversible. Once the gas is bound, it can’t be released back into the environment.
The media used for chemisorption are often impregnated carbons or impregnated aluminas, treated with chemicals designed to neutralise specific gases. For example:
- Potassium permanganate impregnated media oxidizes gases like H2S and SO2.
- Acidic impregnations remove basic gases like ammonia.
- Alkaline impregnations capture acidic gases like NOx.
How Chemisorption Works in Air Filtration
- Air enters the gas phase filter, carrying corrosive gases.
- Targeted gas molecules contact the impregnated media.
- Chemical reactions occur, converting harmful gases into harmless solids that remain within the media.
This chemical reaction ensures the gases are permanently removed from the air stream.
Applications of Chemisorption in HVAC Systems

- Data Centres: Protects sensitive electronics from corrosive gases that cause circuit board failures.
- Industrial Control Rooms: Maintains system reliability by preventing sensor and equipment corrosion.
- Hospitals and Laboratories: Ensures sterile environments free from harmful reactive gases.
- Petrochemical Plants and Refineries: Protects equipment and staff from toxic emissions.
Related: The Critical Role of Air Quality in Healthcare Facilities
Final Thoughts

Chemisorption provides the critical shield by chemically binding and neutralising corrosive gases. It protects sensitive equipment, ensures operational reliability, and upholds safety in high-stakes environments. Chemisorption creates a gas phase filtration strategy that meets the diverse needs of industries where clean air is not optional, but essential.
Read More: Air Filtration for Laboratory
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